个人简介
2013和2016年于宁夏大学分别获理学学士、理学硕士学位。硕士期间,师从顾培明教授从事α-重氮酯与内消旋二叠氮醇的去对称反应研究。2016年至2020年于兰州大学,师从舒兴中教授从事镍催化(不对称)还原烯基化反应研究,获理学博士学位。2021年至2024年,在太阳集团tyc151赵玉明教授课题组从事复杂活性天然产物的全合成研究。2025年1月至今,在太阳成集团tyc151cc从事教学和科研工作。
目前主要研究兴趣为天然产物合成导向的有机合成方法学、不对称催化反应,迄今已在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Org. Lett. 等国际顶级刊物上发表学术论文6篇,主持国家自然科学基金青年项目一项。
代表性成果
(1) Jin-Bao Qiao+, Long Meng+, Jia-Yi Pei, Hui Shao, and Yu-Ming Zhao*. Total Synthesis of Ryanodane Diterpene Garajonone and 3-epi-Garajonone. Angew. Chem. Int. Ed. 2024, 63, e202417647.
(2) Ya-Kui Sun+, Jin-Bao Qiao+, Yu-Meng Xin, Qin Zhou, Zhi-Hua Ma, Hui Shao, and Yu-Ming Zhao*. Total Synthesis of Metaphanine and Oxoepistephamiersine. Angew. Chem. Int. Ed. 2023, 62, e202310917.
(3) Jin-Bao Qiao+, Ya-Qian Zhang+, Qi-Wei Yao, Zhen-Zhen Zhao, Xue-Jin Peng, Xing-Zhong Shu*. Enantioselective Reductive Divinylation of Unactivated Alkenes by Nickel-Catalyzed Cyclization Coupling Reaction. J. Am. Chem. Soc. 2021, 143, 12961.
(4) Jin-Bao Qiao, Zhen-Zhen Zhao, Ya-Qian Zhang, Kai Yin, Zhi-Xiong Tian, and Xing-Zhong Shu*. Allylboronates from Vinyl Triflates and ɑ-Chloroboronates by Reductive Nickel Catalysis. Org. Lett. 2020, 22, 5085.
(5) Zhi-Xiong Tian+, Jin-Bao Qiao+, Guang-Li Xu, Xiaobo Pang, Liangliang Qi, Wei-Yuan Ma, Zhen-Zhen Zhao, Xue-Yuan Liu, Xing-Zhong Shu*. Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes. J. Am. Chem. Soc. 2019, 141, 7637.
(6) Jin-Bao Qiao, Yu-Ming Zhao, and Peiming Gu*. Asymmetric Intramolecular Desymmetrization of meso α, α’-Diazido Alcohols with Aryldiazoacetates: Assembly of Chiral C3-Fragments with Three Continuous Stereocenters. Org. Lett. 2016, 18, 1984.